If you decide to use the btrfs data (or/and metadata) replication, you will see the df command reports you your storage get used twice as fast as you expect. Btrfs doesn't act as for example mdadm. Each file will get striped at the block level across all devices available depending on the replication policy selected.

Create a new test file system

root@blackbox:~# mkfs.btrfs -m raid1 -d raid1 -L btrfs01 /dev/sdb /dev/sdc

WARNING! - Btrfs Btrfs v0.19 IS EXPERIMENTAL
WARNING! - see http://btrfs.wiki.kernel.org before using

adding device /dev/sdc id 2
fs created label btrfs01 on /dev/sdb
     nodesize 4096 leafsize 4096 sectorsize 4096 size 298.02GB
Btrfs Btrfs v0.19
root@blackbox:~#

Mount it

root@blackbox:~# mkdir /mnt/btrfs01

root@blackbox:~# mkdir /mnt/btrfs01
root@blackbox:~# mount /dev/sdb /mnt/btrfs01/

Check the capacity available

root@blackbox:~# df -h -F btrfs
Filesystem            Size  Used Avail Use% Mounted on
/dev/sdb              299G   56K  296G   1% /mnt/btrfs01
root@blackbox:~#

Create a new file (dd)

root@blackbox:~# dd if=/dev/zero of=/mnt/btrfs01/file.10G bs=1M count=$((10*1024))
10240+0 records in
10240+0 records out
10737418240 bytes (11 GB) copied, 176.188 s, 60.9 MB/s
root@blackbox:~#

Check how much space this file uses on the file system

root@blackbox:~# df -h -F btrfs
Filesystem            Size  Used Avail Use% Mounted on
/dev/sdb              299G   21G  276G   7% /mnt/btrfs01
root@blackbox:~#

root@blackbox:~# btrfs-show
Label: btrfs01  uuid: d2b77569-a8be-4ec7-862a-d0fc1e6c8511
     Total devices 2 FS bytes used 10.01GB
     devid    1 size 149.01GB used 12.03GB path /dev/sdb
     devid    2 size 149.01GB used 12.01GB path /dev/sdc

Btrfs Btrfs v0.19
root@blackbox:~#

Get the usage explanation from btrfs tool

root@blackbox:~# btrfs filesystem df /mnt/btrfs01/
Data, RAID1: total=11.00GB, used=10.00GB
Data: total=8.00MB, used=0.00
System, RAID1: total=8.00MB, used=4.00KB
System: total=4.00MB, used=0.00
Metadata, RAID1: total=1.00GB, used=14.11MB
Metadata: total=8.00MB, used=0.00
root@blackbox:~#